See at the End from the PLESK 10 Forum : ( One Server with one Master-IP and multiple other IPs )
http://forum.parallels.com/showthread.php?258523
After editing the postfix master.cf : "myhostname=mail.domainIP2.com"
telnet mail.domainIP2.com 25
220 Servername.server.com ESMTP Postfix
telnet mail.domainIP2.com 587
220 mail.domainIP2.com ESMTP Postfix
Port 587 ok but Port 25 is not ok
Please fix it as soon as possible
http://forum.parallels.com/showthread.php?258523
After editing the postfix master.cf : "myhostname=mail.domainIP2.com"
telnet mail.domainIP2.com 25
220 Servername.server.com ESMTP Postfix
telnet mail.domainIP2.com 587
220 mail.domainIP2.com ESMTP Postfix
Port 587 ok but Port 25 is not ok
Please fix it as soon as possible