By default qmail already uses 2 ports :
Standard SMTP on port 25
and
SMTPS (SMTP/SSL) on port 465
Then you can try the port 465.
Or
you can also add a new port for SMTP.
Modify the file /etc/services
Add a line like this :
smtp your-port/tcp
smtp your-port/udp
ex:
smtp 26/tcp
smtp 26/udp
BUT DON'T REMOVE the lines
smtp 25/tcp
smtp 25/udp
Save and close the file /etc/services
Then restart the xinetd service with
service xinetd restart
That's all.